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Modern Terpyridine Chemistry by Ulrich S. Schubert;Harald Hofmeier;George R. Newkome

By Ulrich S. Schubert;Harald Hofmeier;George R. Newkome

The 1st publication to didactically illustrate this actual, favourite category of supramolecular building-blocks covers subject matters starting from terpyridine syntheses, through their chemistry and houses, supramolecular buildings, and multinuclear steel complexes, correct as much as functionalized polymers, 3D-architectures, and surfaces.Invaluable for college students and academics in chemistry and biochemistry, fabrics scientists, in addition to polymer, advanced and physicochemists.

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Rev. 2004, 33, 373-399 by permission of The Royal Society of Chemistry. Modern Terpyridine Chemistry. U. S. Schubert, H. Hofmeier, G. R. Newkome Copyright © 2006 WILEY-VCH Verlag GmbH & Co. 1 Stability constants of [Ru(tpy)2]2+ complexes measured in water [5]. 2 Thermal stability (temperature of 5% weight loss in °C) of terpyridine ligands and metal complexes [7]. Terpyridine ligands Bisterpyridine complexes H 225 Mn2+ 315 5,5″-dimethyl 245 Hg2+ 336 Co2+ 371 Zn2+ 390 Terpyridine ligands, as well as their corresponding metal complexes, were also investigated regarding their thermal stability utilizing thermogravimetric analysis (TGA).

Depending on the specific metal ion, complexes can show different stabilities, as expressed in the stability constants (K values), where K1 represents the monocomplex (1 : 1) and K2 the bis-complex (2 : 1) [5]. 1). * Parts of this chapter are reproduced from Chem. Soc. Rev. 2004, 33, 373-399 by permission of The Royal Society of Chemistry. Modern Terpyridine Chemistry. U. S. Schubert, H. Hofmeier, G. R. Newkome Copyright © 2006 WILEY-VCH Verlag GmbH & Co. 1 Stability constants of [Ru(tpy)2]2+ complexes measured in water [5].

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