By James E. Mark, Burak Erman, Mike Roland
The 4e of The technological know-how and expertise of Rubber offers a wide survey of elastomers with specific emphasis on fabrics with a rubber-like elasticity. As in earlier versions, the emphasis continues to be on a unified therapy of the cloth, exploring chemical points akin to elastomer synthesis and curing, via fresh theoretical advancements and characterization of equilibrium and dynamic homes, to the ultimate functions of rubber, together with tire engineering and production. up-to-date fabric stresses the continual courting among ongoing study in synthesis, physics, constitution and mechanics of rubber know-how and business functions. precise awareness is paid to fresh advances in rubber-like elasticity idea and new processing strategies for elastomers. intriguing new advancements in eco-friendly tire production and tire recycling are covered.
- Provides a whole survey of elastomers for engineers and researchers in a unified therapy: from chemical elements like elastomer synthesis and curing to the ultimate purposes of rubber, together with tire engineering and manufacturing
- Contains vital updates to numerous chapters, together with elastomer synthesis, characterization, viscoelastic habit, rheology, reinforcement, tire engineering, and recycling
- Includes a brand new bankruptcy at the burgeoning box of bioelastomers
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Additional resources for Science and technology of rubber
ACKNOWLEDGMENTS The reader is referred to the classic survey of rubber elasticity by Treloar  and to three recent reviews that give fuller accounts of the molecular theory [9, 35, 36]. The author thanks Mr. R. A. Paden for drawing several of the figures. REFERENCES 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. P. J. Flory, “Statistical Mechanics of Chain Molecules,” Wiley-Interscience, New York, 1969. J. P. Cotton, B. Farnoux, and G. J. Jannink, J. Chem. Phys. 57, 290 (1972). M. C. Morris, J. Appl. Polm.
CLASSIFICATION OF POLYMERIZATION REACTIONS AND KINETIC CONSIDERATIONS Historically polymers have been divided into two broad classes: condensation polymers and addition polymers [11, 14, 15]. Flory [11, p. 37] has defined these as follows: condensation polymers, in which the molecular formula of the structural unit (or units) lacks certain atoms present in the monomer from which it is formed, or to which it may be degraded by chemical means, and addition polymers, in which the molecular formula of the structural unit (or units) is identical with that of the monomer from which the polymer is derived.
A. N. Gent, J. Polym. Sci. Poly. Symp. 28, 625 (1958). ~ 2 Polymerization: Elastomer Synthesis RODERIC P. QUIRK The Maurice Morton Institute of Polymer Science The University of Akron Akron, Ohio DEANNA L. GOMOCHAK PICKEL Research Laboratories Eastman Chemical Company Kingsport, Tennessee I. II. III. IV. V. VI. VII. VIII. IX. Introduction Classification of Polymerization Reactions and Kinetic Considerations Polyaddition/Polycondensation Chain Polymerization by Free Radical Mechanism Emulsion Polymerization Copolymerization Chain Polymerization by Cationic Mechanism Chain Polymerization by Anionic Mechanism Stereospecific Chain Polymerization and Copolymerization by Coordination Catalysts X.